Genesis 19:24 in the King James Version
Then the LORD rained upon Sodom and upon Gomorrah brimstone and fire from the LORD out of heaven;
Context
23 The sun had risen on the earth when Lot came to Zoar.
24 Then the LORD rained on Sodom and on Gomorrah sulfur and fire from the LORD out of the sky.
25 He overthrew those cities, all the plain, all the inhabitants of the cities, and that which grew on the ground.